Back in 2005 Kimberly produced two very popular webcast series - an 11-part webcast series for TechNet called SQL Server 2005 for the IT Professional and a 10-part webcast series for MSDN called A Primer for Proper SQL Server Development. The webcast links and blog posts were broken for quite a while but now they're all fixed up and working again. I've created some web pages that link to all the webcasts and blog posts, along with abstracts. I've also included some more recent ones too and will be adding to the list over the next few weeks.
There's over 30 hours of good stuff to watch - check them out at http://www.sqlskills.com/webcasts.asp